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Recycled Wind Turbines Could Be Made into Plexiglass, Diapers or Gummy Bears

2022-08-26
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The blades of a wind turbine are typically designed to be replaced about every 20 years. This means that, as wind energy becomes more popular, more and more of these hulking fiberglass structures will be discarded, and many of them could end up buried in the ground. To encourage recycling the blades instead, one research team has developed a binding resin—the ingredient that holds their fibrous material together—that can be transformed into more valuable substances.

“We’ve specifically designed a system with the end of life in mind,” says John Dorgan, a professor of chemical engineering and materials science at Michigan State University, who worked on developing the new resin. After being used for years to strengthen wind turbine blades or other structures, the resin can be recycled back into another turbine blade or downcycled into a composite material that can be used to make plastic products. It can also be processed to produce more valuable chemicals: these upcycled options include the shatter-resistant acrylic plexiglass, a superabsorbent polymer used in diapers and the food preservative potassium lactate—which Dorgan used to make gummy bears that he then ate.

Wind turbine blades are typically 170 feet long, roughly the length of an Olympic-sized swimming pool. But because bigger turbines can capture more energy, some offshore wind farms are investing in taller installations that can sport blades nearly twice as long. When these massive blades are damaged or reach the end of their lifetime, they must be retired from use. By 2050, experts estimate that more than two million tons of blade material could be decommissioned each year.

There are two main obstacles to recycling these structures. “To start with is just the fact that they’re very large, and they’re meant to be very durable—to last in the weather for 20 or more years. So they’re just a hard thing to disassemble and move around,” explains Aubryn Cooperman, a wind energy analyst at the National Renewable Energy Laboratory, who was not involved in the new resin’s development. Another problem “is that they’re made from materials that are as low-cost as possible [that will] still get the performance you need.” For maximum efficiency, wind turbine blades must be both light and strong, so engineers typically craft them from fiberglass bonded together with a polymer resin. In theory, this material can be recycled, but researchers say the resulting product is not particularly valuable. “The main problem is: it’s simply uneconomic to do it,” Dorgan says. “It’s cheaper to just bury it in the ground than it is to reprocess it into something useful.”

To solve this problem, recycling wind turbine blades must become easier and more profitable. Several companies in the renewable energy industry—including Siemens Gamesa, General Electric and Vestas—are working on this issue, Cooperman says. “Anything that makes it easy to recycle, that makes it less costly to recycle, increases the chances of more recycling happening,” she notes.

Dorgan and his colleagues decided to develop a new polymer resin that could bind a large fiberglass structure firmly together while it is in use and that could be turned into a variety of products when the time comes to retire the blade. The team produced a syrupy resin by dissolving polylactide, a polymer derived from plants, in a synthetic monomer called methyl methacrylate (MMA). Next, the researchers used vacuum pressure to pull the resin through glass fibers. After the fibers had been impregnated with the liquid, the resin hardened, producing solid fiberglass panels. The same process can be used to make larger structures, including wind turbine blades and boat hulls. The team presented the work this week at a meeting of the American Chemical Society.

When the time came to recycle their experimental fiberglass panels, the researchers had a few options. In one, they could crush up the panels and add an additional polymer, producing a plastic material that could be transformed into other objects through injection molding. This short-fiber composite might become the basis of computer housings or other objects but would not be particularly valuable, Dorgan says. Another option was to make strong new panels from the remains of the old ones: the team soaked the panels in the MMA monomer, which dissolved the hardened resin—then the researchers physically removed the glass fibers. The recovered “syrup” was used to make fresh fiberglass panels, which had the same physical properties as the originals.

But the leftover resin also has other potential uses. “What would really drive recycling of wind turbines is if you could turn them into something that’s worth more money or by using it to [make high-value] products out of it,” Dorgan says. For instance, putting the recovered resin through different chemical reactions allowed the team to extract new compounds. One substance produced this way was polymethyl methacrylate, an acrylic polymer better known as plexiglass. This transparent, shatter-proof substance is valued as an alternative to glass in a vast variety of goods, ranging from windows to car headlights. Cooking the resin at a high temperature produced poly(methacrylic acid), a superabsorbent material used in diapers and other products. A little more processing resulted in potassium lactate, which is added to a variety of foods as a preservative. Although Dorgan did use it to make his own version of gummy bears, he does not necessarily see homemade candy as the primary way to improve the recyclability of wind turbine blades. His goal is to encourage recycling by changing attitudes.

“I’m trying to push the boundaries of how people think about recycling,” he explains. “It’s about creating additional options and getting people to think about ‘What really are the limits on recycling?’ And as far as I know, nobody’s ever reprocessed a durable composite material into something that can be eaten.”

参考译文
可回收的风力涡轮机可以制成有机玻璃,尿布或小熊软糖
风力涡轮机的叶片通常每20年更换一次。这意味着,随着风能变得越来越流行,越来越多的这种笨重的玻璃纤维结构将被丢弃,其中许多最终可能会被埋在地下。为了鼓励回收利用这些叶片,一个研究小组开发了一种粘合树脂,这种树脂可以将纤维材料粘合在一起,并将其转化为更有价值的物质。密歇根州立大学化学工程和材料科学教授约翰·多根(John Dorgan)说:“我们专门设计了一种考虑到生命终结的系统。”多根致力于开发这种新树脂。在被用于加强风力涡轮机叶片或其他结构多年后,树脂可以回收到另一个涡轮机叶片或降级为复合材料,可以用来制造塑料产品。它还可以被加工成更有价值的化学品:这些升级回收的选择包括防碎的丙烯酸有机玻璃、用于尿布的高吸水性聚合物和食品防腐剂乳酸钾——多根曾用乳酸钾制作他后来吃掉的小熊软糖。风力涡轮机的叶片通常有170英尺长,大致相当于一个奥运会大小的游泳池的长度。但是,由于更大的涡轮机可以捕获更多的能量,一些海上风力发电场正在投资修建更高的设施,这样叶片的长度可以达到近两倍。当这些巨大的刀片损坏或寿命结束时,它们必须退出使用。专家估计,到2050年,每年将有超过200万吨的叶片材料退役。回收这些结构有两个主要障碍。“首先,它们非常大,而且非常耐用——在恶劣的天气中可以使用20年或更长时间。因此,它们很难拆卸和移动,”国家可再生能源实验室(National Renewable energy Laboratory)的风能分析师奥布林·库珀曼(Aubryn Cooperman)解释道,他没有参与这种新树脂的开发。另一个问题是,“它们的材料成本尽可能低,但仍能获得所需的性能。”为了达到最大的效率,风力涡轮机的叶片必须既轻又强,所以工程师们通常用玻璃纤维和聚合物树脂粘合在一起来制造它们。理论上,这种材料是可以回收的,但研究人员表示,由此产生的产品并不是特别有价值。“主要问题是:这样做根本不经济,”道根说。“直接埋在地下比重新加工成有用的东西更便宜。”为了解决这个问题,回收风力涡轮机叶片必须变得更容易,更有利可图。库伯曼说,可再生能源行业的几家公司——包括西门子伽美萨(Siemens Gamesa)、通用电气(General Electric)和维斯塔斯(vestas)——正在研究这个问题。她指出:“任何使其易于回收、回收成本更低的东西,都会增加更多回收发生的可能性。”Dorgan和他的同事们决定开发一种新的聚合物树脂,这种树脂可以在使用过程中将大型玻璃纤维结构牢固地粘合在一起,当刀片退役时,它可以被制成各种产品。该团队通过将聚乳酸(一种从植物中提取的聚合物)溶解在一种名为甲基丙烯酸甲酯(MMA)的合成单体中,生产出一种糖浆型树脂。接下来,研究人员使用真空压力将树脂拉过玻璃纤维。当纤维被液体浸渍后,树脂变硬,产生实心的玻璃纤维板。同样的过程可以用于制造更大的结构,包括风力涡轮机叶片和船体。该团队本周在美国化学学会的一次会议上介绍了这项工作。 当需要回收他们的实验玻璃纤维面板时,研究人员有几个选择。其中一种是,他们可以粉碎面板,添加额外的聚合物,生产出一种可以通过注射成型转化为其他物体的塑料材料。道根说,这种短纤维复合材料可能成为电脑外壳或其他物体的基础,但不会特别有价值。另一种选择是用旧面板的剩余部分制作坚固的新面板:研究小组将面板浸泡在MMA单体中,它溶解了硬化的树脂,然后研究人员物理地去除玻璃纤维。回收的“糖浆”被用来制造新的玻璃纤维面板,这些面板的物理性能与原来的相同。但剩余的树脂还有其他潜在用途。“真正能推动风力涡轮机回收利用的是你是否能把它们变成更值钱的东西,或者用它来[制造高价值的]产品,”多根说。例如,通过将回收的树脂进行不同的化学反应,团队可以提取出新的化合物。用这种方法生产的一种物质是聚甲基丙烯酸甲酯,这是一种丙烯酸聚合物,更广为人知的名字是有机玻璃。这种透明的、防碎的物质被认为是各种各样商品的玻璃替代品,从窗户到汽车前灯。在高温下烹饪树脂会产生聚(甲基丙烯酸),一种用于尿布和其他产品的高吸水性材料。稍微多一点的加工就产生了乳酸钾,它被添加到各种食物中作为防腐剂。虽然道根确实用它制作了自己的小熊软糖,但他并不认为自制糖果是提高风力涡轮机叶片可回收性的主要方法。他的目标是通过改变人们的态度来鼓励回收利用。他解释说:“我正在尝试挑战人们对回收的看法。”“这是关于创造更多的选择,让人们思考‘回收的真正限制是什么?’据我所知,还没有人把耐用的复合材料再加工成可以吃的东西。”
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